Phosphate Sodium Boiler Ratios

Control System Improves Reliability and Safety of Recovery Boilers …

operating the boiler chemistry within a specified range of sodium-to-phosphate ratios [5,6], presented in Figure 2 as a graph of pH versus phosphate for various pressures. Operating above the range can result in caustic corrosion and

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Considerations for High Pressure Boiler Chemical Treatment - …

di-basic phosphate in the boiler (sodium to phosphate molar ratio less than 3.0 to 1), caustic (NaOH) cannot concentrate and cause corrosion. This assures that all the sodium is associated with phosphate and no free NaOH is in solution. By maintaining the

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High-Pressure Steam Cycle and Boiler Water Treatment

ULTRAMARINESM HP BWT Program • Drew Marine pioneered the "modified phosphate-pH treatment" – Utilizes disodium orthophosphate and caustic so that no "free caustic" is generated in the boiler water – Sodium to phosphate ratio is approximately 2.75:1 and

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Boiler Treatment Chemicals Suppliers| B&V Chemicals

BV666. Polymer and phosphate based formulation. A boiler feedwater treatment for the control of scale. Suitable for low hardness, softened and de-alkalised feedwater. BV802. Polymer and phosphate based formulation. A powdered dispersant and sludge conditioner for steam raising plant. Includes an antifoam. BV450.

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5-2 Recovery Boiler Water Treatment - TAPPI

1994/8/22 · Thus the maintenance of a 3:1 sodium phosphate ratio in boiler water may not provide positive protection against caustic-concentration-type corrosion damage. One form of pH/phosphate control maintains a Na:PO 4 ratio that does not exceed 2.6. (A Na:PO 4

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internal boiler treatment

OptiSperse* HP5465 internal boiler treatment • Outstanding protection against metal oxide deposition and caustic corrosion. caustic gouging. • Optimum control with tailored sodium to phosphate ratio • Easy to handle liquid formulation description and use

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Boiler water treatment - Lenntech

Sodium carbonate partially breaks down at high temperature to sodium hydroxide (caustic) and carbon dioxide. High temperatures in the boiler water reduce the solubility of calcium sulphate and tend to make it precipitate out directly on the boiler metal as scale.

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Ph And Phosphate Concentration In Bfw And Steam Drum - …

2007/10/14 · Ph And Phosphate Concentration In Bfw And Steam Drum - posted in Industrial Professionals: Boiler feed water (BFW) pH is to be maintained in the range of 8.0 to 9.5(guidelines) where as in steam drum pH maintaining guidelines is in the range of 9.5 to 11.0. Pressure of steam drum is 34 barg. Since dosing of PO4 (Trisodium phosphate is dosing in …

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Boiler system pH/phosphate program control method - NALCO …

1999/4/25 · Hollander, Orin. "Control of Sodium to Phosphate Ratio in Real Time in a Boiler in the Presence of Additives and Impurities." Paper presented at the CORROSION 99, San Antonio, Texas, April 1999. Download citation file: Ris (Zotero) Reference Manager EasyBib

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Power plant and calculations: How do you calculate Boiler HP dosing system capacity

2020/7/21 · Power plant and calculation site basically includes the detailed study of power plant operation and maintenance, its related all calculations and thumb rules. Phosphate treatment is preferred in drum type boilers. In this Phosphate especially Tri sodium phosphate is added at the boiler drum which is operating at high pressure (so called HP dosing system) through …

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What is the calculation of sodium and phosphate ratio for high …

1992/5/1 · @article{osti_5066607, title = {Program determines sodium-to-phosphate ratio in boiler water}, author = {Buecker, B}, abstractNote = {This paper discusses sodium phosphate compounds, notably trisodium and disodium phosphate which have been used for years at many fossil-fired power plants for boiler water treatment.

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Phosphate concentration-pH of boiler water when using …

Phosphate chemistry is widely used in fossil-fired utility boilers and many of these phosphate programs use the sodium to phosphate ratio as the controlling parameter. This paper steps through the fundamental chemical analyses to determine a systems Na/PO

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Water Handbook - Preboiler & Industrial Boiler Corrosion Control | …

Sodium sulfite. 3 lb of sodium sulfite and 3 lb of caustic soda should be added per 1000 gal of water contained in the boiler (minimum 400 ppm P-alkalinity as CaCO3 and 200 ppm sulfite as SO3). Hydrazine. 5 lb of a 35% solution of hydrazine and 0.1 lb of ammonia or 2-3 lb of a 40% solution of neutralizing amine can be added per 1000 gal (minimum 200 ppm hydrazine and …

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EP0640747A1 - Boiler system pH/phosphate program control …

A pH/phosphate program in a boiler water system is controlled by: (1) determining the feed rate of the phosphate to the boiler by adding to a phosphate-feed stream containing the phosphate feeding to the boiler a phosphate-feed tracer in known proportion to the

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Sodium to phosphate ratios|INIS

Boiler system pH/phosphate program control method - NALCO

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Water Handbook -Boiler Deposits: Occurrence And Control | SUEZ

Scale may form as calcium silicate in one boiler and as sodium iron silicate in another. Compared to some other precipitation reactions, such as the formation of calcium phosphate, the crystallization of scale is a slow process.

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why trisodium phosphate dosing in boiler drum – CFBC Boiler …

Trisodium Phosphate dosing is done in boiler drum which react with scale forming salts like calcium cloride,calcium sulphate. 3 cacl2 + 2 na3 po4 = ca3 (po4)2 +6 nacl the sludge collected in bottom header which can be removed by operating low points drain. phosphate dosing is done to prevent scale formation in boiler.

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Boiler feed water

Topic – 1 Boiler feed water 1 .Definition: The setup used to produce steam in industries is known as 'Boiler'. 1 Na3PO4 Tri sodium Phosphate highly acidic water 2 Na2HPO4 Di sodium hydrogen Phosphate slightly acidic water 3 NaH2PO4 Sodium di 2 [ Na4

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Phosphate concentration-pH of boiler water when using …

It is recommended that sodium to phosphate molar ratio (Na:PO 4 ) must be kept below 2.6 in this program, achieved by adding specific mixture of Na 3 PO 4 and Na 2 HPO 4 to boiler drum [22,24,25].

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Calculating Boiler Chemical Requirements – Water Technology …

2016/10/26 · High Sodium/phosphate Ratio In RG Boilers. Said92441322 (Chemical) (OP) 26 Oct 16 11:42. Dear Experts, In our complex we are currently facing higher sodium to phophate ratios problem in all our Boilers. We have an integrated BFW system where interconnected de-aerators which are common for both HP BFW pumps and KP BFW pumps are installed.

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Program determines sodium-to-phosphate ratio in boiler water …

Calculating Boiler Chemical Requirements – Water

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Control of Sodium to Phosphate Ratio in Real Time in a Boiler in …

Boiler system pH/phosphate program control method - NALCO

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Chemical Treatment Requirements for Steam and Hot Water …

2017/6/12 · The molar ratio of sodium to phosphate is known as the congruent ratio. As this reaction occurs, sodium hydroxide forms in the boiler water as follows: Na 3 PO 4 + 0.2H 2 O —– Na 2.8 H 0.2 PO 4 + 0.2NaOH The free caustic soda (NaOH) is then available to

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Calculating Boiler Chemical Requirements – Water Technology …

2017/6/26 · Monosodium phosphate (anhydrous) 59.1% 40.0 Sodium hexametaphosphate (anhydrous) 67.5 to 69.0% 34.0 Sodium tripolyphosphate (anhydrous) 57.0 to 58.0% 40.9 P 2 O 5 23.7 From these figures we can determine the equivalent weight of any 2 0 5

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Boiler Water Treatment

2/18/2014 4 PRETREATMENT EXTERNAL TREATMENT Clarification Filtration Ion Exchange Sodium Zeolite Ultrapure Dealkalizers Softeners 2/18/2014 5 Basic Boiler System Makeup External Treatment Steam Vent Blowdown Feedwater Return Condensate

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coordinated phosphate control for boiler – Industrial Boiler Supplier

2019/2/28 · History of Coordinated Phosphate pH Control … caustic" is generated in the boiler water – Sodium to phosphate ratio is approximately 2.75:1 and provides margin of safety for good control of the program Big Picture of Water Treatment Chemicals – Veolia

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High Sodium/phosphate Ratio In RG Boilers - Chemical process …

2012/8/21 · Sodium phosphate is a generic term for the salts of sodium hydroxide and phosphoric acid (soluble in water). Monosodium phosphate (NaH2PO4), also known as anhydrous monobasic sodium phosphate and

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Can anyone explain the use of Sodium Hexametaphosphate in Boilers…

Sodium Hexametaphosphate in Boilers added depending on the feed water quality and blow-down rate that control sludge accumulation. As a first guideline, for water with high calcium content you can

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Program determines sodium-to-phosphate ratio in boiler water (J…

Boiler system pH/phosphate program control method - NALCO

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US5747342A - Methods and apparatus for monitoring and controlling PH phosphate and sodium to phosphate ratio in boiler …

Methods and apparatus for monitoring and controlling pH, phosphate, and sodium to phosphate ratio in boiler systems operating with captive alkalinity chemistry are described. The methods for monitoring and controlling these parameters include the steps of determining the phosphate concentration via FIA, determining the pH, and using these values to determine the sodium to …

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Uses & Applications of Phosphates in Cooling Water Treatment

phosphate. A slightly basic pH should be maintained in the boiler feedwater system. The American Society for Mechanical Engineers (ASME) suggests feed water to be kept at a pH of 8.3-10.5. Sodium phosphates help fulfill this requirement. Boiler System

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QUESTIONS AND ANSWERS Phosphate Hideout - Steam Turbine, Steam Boiler…

sodium:phosphate ratio. It will also make the condition which causes the hideout to worsen by allowing acidic conditions to occur. Keep the phosphate at the lowest end of …

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Plant Service Bulletin: Boiler Water Phosphate Chemistry

zone. Major quantities of sodium iron phosphate were found in the affected tubes, indicating that the sodium phosphate from the boiler water had participated in the corrosion mechanism. Figure 1 and Figure 2 show the corrosion. Recommendations 1. 2. 3.

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coordinated phosphate control for boiler – Industrial Boiler Supplier

2019/2/28 · History of Coordinated Phosphate pH Control … caustic" is generated in the boiler water – Sodium to phosphate ratio is approximately 2.75:1 and provides margin of safety for good control of the program Big Picture of Water Treatment Chemicals – Veolia

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